Title:
Comparison of the Thermocatalytic Reforming of Sewage Sludge to its Pyrolysis
Author(s):
Onyishi, H., Fox, A., Pech, J., Neidel, J., Daschner, R., Apfelbacher, A., Hornung, A.
Document(s):
Paper
Slide presentation
Abstract:
This work investigates the fundamental differences between pyrolysis and thermocatalytic reforming (TCRŽ). The TCRŽ, developed by the Fraunhofer UMSICHT, is an extension of pyrolysis in that it involves intermediate pyrolysis in an auger reactor and catalytic reforming in a post-reformer. A TCRŽ plant can be converted back to a pyrolysis plant when the post-reforming phase is deactivated. In this work, sewage sludge is tried in both the TCRŽ and the pyrolysis arrangements using a lab-scale TCRŽ plant. The pyrolysis experiments are carried out at temperatures of 450 and 600 °C while the TCRŽ experiments are carried out a reactor temperature of 450 °C each and post-reformer temperatures of 600 and 750 °C. The results show that intermediate pyrolysis produces greater biooil and process water yields and the TCRŽ generally produces greater amounts of biochar while their biogas yields seem the same. But it is observed that the hydrogen fraction of the gas from pyrolysis is minimal while that of the gas from the TCRŽ is up to 40 vol.%. In either case, the hydrogen fraction increases with increasing prevailing temperature and, in the case of pyrolysis, with increasing solid residence time. The results agree with predictions from literature. Therefore, the TCRŽ can be said to be the more suited technology for the valorisation of biomass.
Keywords:
biofuel, biomass, hydrogen, pyrolysis, thermocatalytic reforming
Topic:
Biomass Conversion to Intermediate Bioenergy Carriers and Sustainable Biofuels
Subtopic:
Pyrolysis
Event:
32nd European Biomass Conference and Exhibition
Session:
5CO.10.2
Pages:
670 - 674
ISBN:
978-88-89407-24-0
Paper DOI:
10.5071/32ndEUBCE2024-5CO.10.2
Price:
FREE